Here, side by side overlapping takes place. ”Pi bonds are the result of the pairing of unbound p-orbital electrons between two atoms. When two fluorine atoms having opposite spins approach each other, their p orbitals overlap with each other. Here, the electronic configuration of fluorine is F: 1s 2 2s 2 2px 2 2py 2 2pz 1. The formation of fluorine (F 2) molecules is an example of the p-p sigma bond.
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